Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF<sub>6</sub>] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents

Victoria Bennett; Daniel Ikoromo Ziriki

doi:doi:10.11648/j.pse.20220602.11

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Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF₆] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents

Victoria Bennett, Daniel Ikoromo Ziriki

Published in Petroleum Science and Engineering (Volume 6, Issue 2)

Received: 28 June 2022 Accepted: 14 July 2022 Published: 29 July 2022

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Abstract

Insoluble organic solid residues in crude oil can cause staining, lathering, corrosion and contamination of the end product. Hence, removing these insoluble solids from the process stream is pertinent. In this research, samples of insoluble organic solid residues were taken from a single phase bottom hole crude oil, Qua Iboe Light Mobile Nigeria, unlimited. 1-butyl-3-methylimidazolium hexafluorophosphate [BMIm][PF₆] was synthesized, and its effect on the precipitation of insoluble organic solid residues from methanol, ethanol and iso-armyl alcohol was investigated. Results of weight % of insoluble organic solids retrieved from methanol, ethanol and iso-armyl alcohol were 80.1 ± 0.2%, 74 ± 0.3%, 73.3 ± 0.2%, respectively. Comparatively, weights % of insoluble organic solids precipitated with methanol was higher (0.8010 g, 80.1%) than ethanol (0.7400 g, 74%) and iso-armyl alcohol (0.7330 g, 73.3%). This result corroborates the fact that insoluble organic solids are better precipitated from more polar organic solvents. Weights % of insoluble organic solids precipitated from methanol + [BMImPF₆], ethanol + [BMImPF₆] and iso-armyl alcohol + [BMImPF₆] were 80.4 ± 0.1%, 76 ± 0.2% and 75 ± 0.2% respectively. This result implies that organic solvent + [BMImPF₆] combinations yielded greater organic insoluble solid precipitates than those obtained with molecular organic solvents.

Published in	Petroleum Science and Engineering (Volume 6, Issue 2)
DOI	10.11648/j.pse.20220602.11
Page(s)	47-50
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Organic Solvents, Ionic Liquid, Organic Solids

References

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[16]	Omar I. M. A., Aziz M. and Emran K. M. (2021) Impact of ionic liquid [FPIM]Br on the electrodeposition of Ni and Co from an aqueous sulfate bath. Journal of Materials Research and Technology, 12, 170-185.
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APA Style

Victoria Bennett, Daniel Ikoromo Ziriki. (2022). Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents. Petroleum Science and Engineering, 6(2), 47-50. https://doi.org/10.11648/j.pse.20220602.11

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ACS Style

Victoria Bennett; Daniel Ikoromo Ziriki. Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents. Pet. Sci. Eng. 2022, 6(2), 47-50. doi: 10.11648/j.pse.20220602.11

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AMA Style

Victoria Bennett, Daniel Ikoromo Ziriki. Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents. Pet Sci Eng. 2022;6(2):47-50. doi: 10.11648/j.pse.20220602.11

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@article{10.11648/j.pse.20220602.11,
  author = {Victoria Bennett and Daniel Ikoromo Ziriki},
  title = {Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents},
  journal = {Petroleum Science and Engineering},
  volume = {6},
  number = {2},
  pages = {47-50},
  doi = {10.11648/j.pse.20220602.11},
  url = {https://doi.org/10.11648/j.pse.20220602.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.pse.20220602.11},
  abstract = {Insoluble organic solid residues in crude oil can cause staining, lathering, corrosion and contamination of the end product. Hence, removing these insoluble solids from the process stream is pertinent. In this research, samples of insoluble organic solid residues were taken from a single phase bottom hole crude oil, Qua Iboe Light Mobile Nigeria, unlimited. 1-butyl-3-methylimidazolium hexafluorophosphate [BMIm][PF6] was synthesized, and its effect on the precipitation of insoluble organic solid residues from methanol, ethanol and iso-armyl alcohol was investigated. Results of weight % of insoluble organic solids retrieved from methanol, ethanol and iso-armyl alcohol were 80.1 ± 0.2%, 74 ± 0.3%, 73.3 ± 0.2%, respectively. Comparatively, weights % of insoluble organic solids precipitated with methanol was higher (0.8010 g, 80.1%) than ethanol (0.7400 g, 74%) and iso-armyl alcohol (0.7330 g, 73.3%). This result corroborates the fact that insoluble organic solids are better precipitated from more polar organic solvents. Weights % of insoluble organic solids precipitated from methanol + [BMImPF6], ethanol + [BMImPF6] and iso-armyl alcohol + [BMImPF6] were 80.4 ± 0.1%, 76 ± 0.2% and 75 ± 0.2% respectively. This result implies that organic solvent + [BMImPF6] combinations yielded greater organic insoluble solid precipitates than those obtained with molecular organic solvents.},
 year = {2022}
}

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TY  - JOUR
T1  - Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents
AU  - Victoria Bennett
AU  - Daniel Ikoromo Ziriki
Y1  - 2022/07/29
PY  - 2022
N1  - https://doi.org/10.11648/j.pse.20220602.11
DO  - 10.11648/j.pse.20220602.11
T2  - Petroleum Science and Engineering
JF  - Petroleum Science and Engineering
JO  - Petroleum Science and Engineering
SP  - 47
EP  - 50
PB  - Science Publishing Group
SN  - 2640-4516
UR  - https://doi.org/10.11648/j.pse.20220602.11
AB  - Insoluble organic solid residues in crude oil can cause staining, lathering, corrosion and contamination of the end product. Hence, removing these insoluble solids from the process stream is pertinent. In this research, samples of insoluble organic solid residues were taken from a single phase bottom hole crude oil, Qua Iboe Light Mobile Nigeria, unlimited. 1-butyl-3-methylimidazolium hexafluorophosphate [BMIm][PF6] was synthesized, and its effect on the precipitation of insoluble organic solid residues from methanol, ethanol and iso-armyl alcohol was investigated. Results of weight % of insoluble organic solids retrieved from methanol, ethanol and iso-armyl alcohol were 80.1 ± 0.2%, 74 ± 0.3%, 73.3 ± 0.2%, respectively. Comparatively, weights % of insoluble organic solids precipitated with methanol was higher (0.8010 g, 80.1%) than ethanol (0.7400 g, 74%) and iso-armyl alcohol (0.7330 g, 73.3%). This result corroborates the fact that insoluble organic solids are better precipitated from more polar organic solvents. Weights % of insoluble organic solids precipitated from methanol + [BMImPF6], ethanol + [BMImPF6] and iso-armyl alcohol + [BMImPF6] were 80.4 ± 0.1%, 76 ± 0.2% and 75 ± 0.2% respectively. This result implies that organic solvent + [BMImPF6] combinations yielded greater organic insoluble solid precipitates than those obtained with molecular organic solvents.
VL  - 6
IS  - 2
ER  -

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Author Information

Victoria Bennett

Department of Chemical Sciences, Faculty of Basic and Applied Sciences, University of Africa, Sagbama, Nigeria
Daniel Ikoromo Ziriki

Department of Chemical Sciences, Faculty of Basic and Applied Sciences, University of Africa, Sagbama, Nigeria

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Victoria Bennett, Daniel Ikoromo Ziriki. (2022). Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents. Petroleum Science and Engineering, 6(2), 47-50. https://doi.org/10.11648/j.pse.20220602.11

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ACS Style

Victoria Bennett; Daniel Ikoromo Ziriki. Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents. Pet. Sci. Eng. 2022, 6(2), 47-50. doi: 10.11648/j.pse.20220602.11

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AMA Style

Victoria Bennett, Daniel Ikoromo Ziriki. Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents. Pet Sci Eng. 2022;6(2):47-50. doi: 10.11648/j.pse.20220602.11

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@article{10.11648/j.pse.20220602.11,
  author = {Victoria Bennett and Daniel Ikoromo Ziriki},
  title = {Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents},
  journal = {Petroleum Science and Engineering},
  volume = {6},
  number = {2},
  pages = {47-50},
  doi = {10.11648/j.pse.20220602.11},
  url = {https://doi.org/10.11648/j.pse.20220602.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.pse.20220602.11},
  abstract = {Insoluble organic solid residues in crude oil can cause staining, lathering, corrosion and contamination of the end product. Hence, removing these insoluble solids from the process stream is pertinent. In this research, samples of insoluble organic solid residues were taken from a single phase bottom hole crude oil, Qua Iboe Light Mobile Nigeria, unlimited. 1-butyl-3-methylimidazolium hexafluorophosphate [BMIm][PF6] was synthesized, and its effect on the precipitation of insoluble organic solid residues from methanol, ethanol and iso-armyl alcohol was investigated. Results of weight % of insoluble organic solids retrieved from methanol, ethanol and iso-armyl alcohol were 80.1 ± 0.2%, 74 ± 0.3%, 73.3 ± 0.2%, respectively. Comparatively, weights % of insoluble organic solids precipitated with methanol was higher (0.8010 g, 80.1%) than ethanol (0.7400 g, 74%) and iso-armyl alcohol (0.7330 g, 73.3%). This result corroborates the fact that insoluble organic solids are better precipitated from more polar organic solvents. Weights % of insoluble organic solids precipitated from methanol + [BMImPF6], ethanol + [BMImPF6] and iso-armyl alcohol + [BMImPF6] were 80.4 ± 0.1%, 76 ± 0.2% and 75 ± 0.2% respectively. This result implies that organic solvent + [BMImPF6] combinations yielded greater organic insoluble solid precipitates than those obtained with molecular organic solvents.},
 year = {2022}
}

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TY  - JOUR
T1  - Effect of 1-Butyl-3-Methylimdazolium Hexafluorophosphate [BMImPF6] on the Precipitation of Insoluble Organic Solid Residues from Organic Solvents
AU  - Victoria Bennett
AU  - Daniel Ikoromo Ziriki
Y1  - 2022/07/29
PY  - 2022
N1  - https://doi.org/10.11648/j.pse.20220602.11
DO  - 10.11648/j.pse.20220602.11
T2  - Petroleum Science and Engineering
JF  - Petroleum Science and Engineering
JO  - Petroleum Science and Engineering
SP  - 47
EP  - 50
PB  - Science Publishing Group
SN  - 2640-4516
UR  - https://doi.org/10.11648/j.pse.20220602.11
AB  - Insoluble organic solid residues in crude oil can cause staining, lathering, corrosion and contamination of the end product. Hence, removing these insoluble solids from the process stream is pertinent. In this research, samples of insoluble organic solid residues were taken from a single phase bottom hole crude oil, Qua Iboe Light Mobile Nigeria, unlimited. 1-butyl-3-methylimidazolium hexafluorophosphate [BMIm][PF6] was synthesized, and its effect on the precipitation of insoluble organic solid residues from methanol, ethanol and iso-armyl alcohol was investigated. Results of weight % of insoluble organic solids retrieved from methanol, ethanol and iso-armyl alcohol were 80.1 ± 0.2%, 74 ± 0.3%, 73.3 ± 0.2%, respectively. Comparatively, weights % of insoluble organic solids precipitated with methanol was higher (0.8010 g, 80.1%) than ethanol (0.7400 g, 74%) and iso-armyl alcohol (0.7330 g, 73.3%). This result corroborates the fact that insoluble organic solids are better precipitated from more polar organic solvents. Weights % of insoluble organic solids precipitated from methanol + [BMImPF6], ethanol + [BMImPF6] and iso-armyl alcohol + [BMImPF6] were 80.4 ± 0.1%, 76 ± 0.2% and 75 ± 0.2% respectively. This result implies that organic solvent + [BMImPF6] combinations yielded greater organic insoluble solid precipitates than those obtained with molecular organic solvents.
VL  - 6
IS  - 2
ER  -

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