Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw

Khalid M. Mousa; Alaa H. Taha

doi:doi:10.11648/j.pse.20170101.14

| Peer-Reviewed

Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw

Khalid M. Mousa, Alaa H. Taha

Published in Petroleum Science and Engineering (Volume 1, Issue 1)

Received: 29 January 2017 Accepted: 14 February 2017 Published: 2 March 2017

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.

Published in	Petroleum Science and Engineering (Volume 1, Issue 1)
DOI	10.11648/j.pse.20170101.14
Page(s)	17-22
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Kinetics, Isotherm, Modified Wheat Straw

References

[1]	L. Wang, Y. Hung, H. Lo, and C. Yapijakis, Waste treatment in the process industries. 2005.
[2]	S. Jassim, H. Al-Robai, and M. Al-Taee, “Removing Reactive Orange Dye By Using Ceramic Purifier Type (AKPL1),” uobabylon.edu.iq, vol. 50, pp. 121–127, 2013.
[3]	P. Pilipenko, “Cationic Polyelectrolytes as Primary Coagulants for Municipal Wastewater Treatment,” 2007.
[4]	V. Correia, T. Stephenson, and S. Judd, “Characterisation of textile wastewaters‐a review,” Environ. Technol., 1994.
[5]	R. H. Salman, “REMOVAL OF DYES FROM TEXTILE EFFLUENT BY ADSORPTION ONTO OVEN DRIED ALUM SLUDGE,” J. Eng., vol. 6, no. 2, 2010.
[6]	A. Itodo, F. Abdulrahman, L. Hassan, and S. Maigandi, “Intraparticle diffusion and intraparticulate diffusivities of herbicide on derived activated carbon,” Researcher, 2010.
[7]	V. J. Inglezakis and S. G. Poulopoulos, “Adsorption, Ion Exchange and Catalysis: Design of Operations and Environmental Applications,” Elsevier Sci. B V, p. 602, 2006.
[8]	Z. Xu, J. Cai, and B. Pan, “Mathematically modeling fixed-bed adsorption in aqueous systems *,” vol. 14, no. 3, pp. 155–176, 2013.
[9]	W. J. Thomas and B. Crittenden, Adsorption Technology and Design, no. April. 1998.
[10]	R. Ansari, B. Seyghali, and A. Mohammad-Khah, “Highly efficient adsorption of anionic dyes from aqueous solutions using sawdust modified by cationic surfactant of cetyltrimethylammonium bromide,” J. Surfactants, 2012.
[11]	Y. Su, Y. Jiao, C. Dou, and R. Han, “Biosorption of methyl orange from aqueous solutions using cationic surfactant-modified wheat straw in batch mode,” Desalination Water Treat., 2014.
[12]	A. Pirbazari, E. Saberikhah, and S. Kozani, “Fe3 O4–wheat straw: preparation, characterization and its application for methylene blue adsorption,” Water Resour. Ind., 2014.
[13]	S. Kaur, S. Rani, and R. Mahajan, “Adsorption kinetics for the removal of hazardous dye congo red by biowaste materials as adsorbents,” J. Chem., 2012.
[14]	M. Yagub, T. Sen, S. Afroze, and H. Ang, “Dye and its removal from aqueous solution by adsorption: a review,” Adv. Colloid Interface, 2014.
[15]	Y. Ho, J. Ng, and G. McKay, “Kinetics of pollutant sorption by biosorbents: review,” Sep. Purif. Rev., 2000.
[16]	S. Ong, C. Lee, and Z. Zainal, “Removal of basic and reactive dyes using ethylenediamine modified rice hull,” Bioresour. Technol., 2007.
[17]	B. Hameed, “Spent tea leaves: a new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions,” J. Hazard. Mater., 2009.
[18]	M. Desta, “Batch sorption experiments: Langmuir and Freundlich isotherm studies for the adsorption of textile metal ions onto Teff Straw (Eragrostis tef) agricultural waste,” J. Thermodyn., 2013.

Cite This Article

Plain Text BibTeX RIS

APA Style

Khalid M. Mousa, Alaa H. Taha. (2017). Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Petroleum Science and Engineering, 1(1), 17-22. https://doi.org/10.11648/j.pse.20170101.14

Copy | Download

ACS Style

Khalid M. Mousa; Alaa H. Taha. Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Pet. Sci. Eng. 2017, 1(1), 17-22. doi: 10.11648/j.pse.20170101.14

Copy | Download

AMA Style

Khalid M. Mousa, Alaa H. Taha. Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Pet Sci Eng. 2017;1(1):17-22. doi: 10.11648/j.pse.20170101.14

Copy | Download

@article{10.11648/j.pse.20170101.14,
  author = {Khalid M. Mousa and Alaa H. Taha},
  title = {Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw},
  journal = {Petroleum Science and Engineering},
  volume = {1},
  number = {1},
  pages = {17-22},
  doi = {10.11648/j.pse.20170101.14},
  url = {https://doi.org/10.11648/j.pse.20170101.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.pse.20170101.14},
  abstract = {In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw
AU  - Khalid M. Mousa
AU  - Alaa H. Taha
Y1  - 2017/03/02
PY  - 2017
N1  - https://doi.org/10.11648/j.pse.20170101.14
DO  - 10.11648/j.pse.20170101.14
T2  - Petroleum Science and Engineering
JF  - Petroleum Science and Engineering
JO  - Petroleum Science and Engineering
SP  - 17
EP  - 22
PB  - Science Publishing Group
SN  - 2640-4516
UR  - https://doi.org/10.11648/j.pse.20170101.14
AB  - In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.
VL  - 1
IS  - 1
ER  -

Copy | Download

Author Information

Khalid M. Mousa

Department of Chemical Engineering, Al-Nahrain University, Baghdad, Iraq
Alaa H. Taha

Department of Chemical Engineering, Al-Nahrain University, Baghdad, Iraq

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Khalid M. Mousa, Alaa H. Taha. (2017). Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Petroleum Science and Engineering, 1(1), 17-22. https://doi.org/10.11648/j.pse.20170101.14

Copy | Download

ACS Style

Khalid M. Mousa; Alaa H. Taha. Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Pet. Sci. Eng. 2017, 1(1), 17-22. doi: 10.11648/j.pse.20170101.14

Copy | Download

AMA Style

Khalid M. Mousa, Alaa H. Taha. Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw. Pet Sci Eng. 2017;1(1):17-22. doi: 10.11648/j.pse.20170101.14

Copy | Download

@article{10.11648/j.pse.20170101.14,
  author = {Khalid M. Mousa and Alaa H. Taha},
  title = {Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw},
  journal = {Petroleum Science and Engineering},
  volume = {1},
  number = {1},
  pages = {17-22},
  doi = {10.11648/j.pse.20170101.14},
  url = {https://doi.org/10.11648/j.pse.20170101.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.pse.20170101.14},
  abstract = {In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Study of Adsorption Isotherm and Kinetics of Reactive Yellow Dye on Modified Wheat Straw
AU  - Khalid M. Mousa
AU  - Alaa H. Taha
Y1  - 2017/03/02
PY  - 2017
N1  - https://doi.org/10.11648/j.pse.20170101.14
DO  - 10.11648/j.pse.20170101.14
T2  - Petroleum Science and Engineering
JF  - Petroleum Science and Engineering
JO  - Petroleum Science and Engineering
SP  - 17
EP  - 22
PB  - Science Publishing Group
SN  - 2640-4516
UR  - https://doi.org/10.11648/j.pse.20170101.14
AB  - In this study, the adsorption of reactive yellow dye which is one of the most commonly used soluble dyes in textile industries was studied using modified wheat straw, the surface of raw wheat straw was modified with a cationic surfactant CTAB. to understand the adsorption behavior of the reactive yellow, dye the adsorption kinetics and the adsorption isotherm studies have been investigated. Batch experiments was carried out with an initial concentration of 10 mg/L with 0.5 gm of adsorbent to study the contact time of equilibrium and then the adsorption mechanism process using three kinetic models; Pseudo-first, second order and intra-particle model. Isotherm studies was carried out at three different adsorbent amounts (0.1, 0.2, 0.4, 0.6, 0.8 and 1.0) gm to predict the type of adsorption process on the surface (chemical or physical) using three isotherm models; Langmuir, Freundlich and BET models. The results showed that the pseudo-second order is best fitted, intra-particle diffusion kinetic model fitted well to experimental data and is not the only controlling step of adsorption rate, and the adsorption isotherm follows both Langmuir and Freundlich models referring to the chemical adsorption.
VL  - 1
IS  - 1
ER  -

Copy | Download